Determination of pollutions in the surface of water samples from Ogbajarajara river, Nigeria by spectrophotometer and atomic absorption spectrometry before evaluation of health risk assessment
Volume 5, Issue 01, Pages 5-21, Mar 2021 *** Field: Analytical Environmental Chemistry
Abstract
Determination of environmental pollution in the surface water is very important. So, in this study, determination, and health risk assessment were evaluated. The pollutions such as anions, cations, and heavy metals were analyzed in surface water by photometer spectrometry and atomic absorption spectrometry (AAS). TDS for wet and dry seasons go from 122.17±1.74 mg L-1 to 63.80±0.86 mg L-1. The high phosphate levels in both wet and dry seasons are recorded from 60.74±0.61 - 60.27±0.38 mg L-1 in both seasons. Iron values observed range from 8.42±0.06 to 6.28±0.11 mg L-1 in the wet and dry season, Cu was recorded between 0.08±0.01 - 0.07±0.01 mg L-1, Mn recorded from 0.07±0.01 to 0.06±0.01 mg L-1, Zn recorded between 2.29±0.09 - 1.15±0.09 mg L-1, and Pb recorded from 0.69±0.09 to 0.40±0.18 mg L-1 while Cd and Ni were not detected in the study. Water quality index (WQI) values were determined as 549 for wet and 328 for the dry season, the hazard indices for both seasons are below one. The outcomes in this present study showed that the level of Pb in the surface water could present a carcinogenic risk to both adults and children. All heavy metals results were validated by ET-AAS.
References
R.G. Timothy, T. Makoto, K. Henk, J.G. Jason, M.A. Diana, Beneath the surface of global change: Impacts of climate change on groundwater, J. Hydrol., 405 (2011) 532-560. https://doi.org/10.1016/j.jhydrol.2011.05.002
G. Dubnov-Raz, N.W. Constantini, H. Yariv, S. Nice, N. Shapira, Influence of water drinking on resting energy expenditure in overweight children, Int. J. Obesity, 35 (2011) 1295–1300. https://doi.org/10.1038/ijo.2011.130
P.U. Okorie, The challenges of declining freshwater resources, Paper presented at the world environment day conference held at Imo state University Owerri, Nigeria, 2017. http://ijfac.unsri.ac.id/index.php/ijfac/article/view/156
L. Gang, G.X. Sun, X. Ren, S. Luo, Y.G. Zhu, Urban soil and human health: a review, Eur. J. Soil Sci., 69 (2018) 196-215. https://doi.org/10.1111/ejss.12518
J. Anudike, M. Duru, F. Uhegbu, Water quality assessment of Nwangele River in Imo State, Nigeria, J. Ecobiotechnol., 11 (2019) 1-5. https://doi.org/10.25081/jebt.2019.v11.3866
E.A. Ubuoh, S.M.O. Akhionbare, S. Ogbuji, W.N. Akhionbare, Effectiveness of water quality index in assessing water resources, Characteristics in Izombe, Oguta Local government Area of Imo State, Nigeria. I.J.A.B.R., 3 (2013) 31-35. http://www.scienceandnature.org/IJABR_Vol3(1)2013.php
S. Srivastava, V. Sharma, Ultra-portable, smartphone-based spectrometer for heavy metal concentration measurement in drinking water samples, Appl. Water Sci., 11 (2021) 177. https://doi.org/10.1007/s13201-021-01519-w
A. Rotimi Ipeaiyeda, A. Ruth Ayoade, Flame atomic absorption spectrometric determination of heavy metals in aqueous solution and surface water preceded by co-precipitation procedure with copper(II) 8-hydroxyquinoline, Appl, Water Sci., 7 (2017) 4449–4459. https://doi.org/10.1007/s13201-017-0590-9
S. T. Palisoc, R. I. M. Vitto, Highly sensitive determination of heavy metals in water prior to and after remediation using Citrofortunella Microcarpa, Sci. Reports, 11 (2021) 1394. .https://doi.org/10.1038/s41598-020-80672-9
O. V. Rodinkov, A. Y. Pisarev, Sensitivity increase in headspace analysis of hydrocarbons in water by using online selective elimination of gas extractant, Sep. J., 9 (2022) 15. https://doi.org/10.3390/separations9010015
S.C. Ihenetu, F.C. Ihenetu, G.I. Kalu, Determination of heavy metals and physicochemical parameters of crude oil polluted soil from Ohaji Egbema Local government in Imo State, Open J. Yangtze Gas Oil, 2 (2017) 161-167. https://doi.org/10.4236/ojogas.2017.23012
E.E. Christian, W.V. Andrew, J.E. Ngozi, pH variations and chemometric assessment of borehole water in Orji, Owerri Imo State, Nigeria, J. Environ. Anal. Chem., 5 (2018) 1000238. https://doi.org/10.4172/2380-2391.1000238
WHO (World Health Organization), guidelines for drinking water quality (3rd ed.) Vol.1 Recommendation, Geneva, 515, 2007. https://www.who.int/water_sanitation_health/dwq/fulltext.pdf
M. Duru, K. Nwanekwu, Physicochemical and microbial status of Nworie River, Owerri, Imo State, Nigeria, Asian J. Plant Sci. Res., 2 (2012) 433-436. https://www.imedpub.com/articles/physicochemical-and-microbialstatus-of-nworie-river-owerri-imo-state-nigeria.pdf
WHO (World Health Organization), guidelines for drinking water quality (3rd ed.) Vol.1 Recommendation, Geneva, 515, 2004. https://www.who.int/water_sanitation_health/dwq/GDWQ2004web.pdf
E.I. Ugwu, N.E. Uzoma, E.L. Ikechukwu, Study on Physiochemical Parameters of Water Samples from Onuimo River Imo state, Nigeria, South Asian J. Eng. Technol., 2 (2016) 1–8. https://journals.eleyon.org/index.php/sajet
S. C. Ihenetu, V. O. Njoku, A. Chinweuba, F. C. Ibe, and N. B. Ekeoma, A review: Effects of air, water and land dumpsite on human health and analytical methods for determination of pollutants, Anal. Methods Environ. Chem. J. 4 (2021) 80-106. https://doi.org/10.24200/amecj.v4.i03.147
D.W. Macdonald, E.O. Christopher, Pollution studies on Nigerian rivers: heavy metals in surface water of Warri River, Delta State, J. Biodiversity Environ. Sci., 1 (2011) 7-12. https://innspub.net/journal/journal-of-biodiversity-and-environmental-sciences-jbes/
B.A. Amadi, P.C. Chikezie, H.C. Okeoma, Physiochemical characteristics of Nworie river and its effect on liver function on rats, J. Nigeria Environ. Sci., 3 (2006)183-187. https://nijest.com/about-nijest/
A.W. Verla, E.N. Verla, C.E. Amaobi, C.E. Enyoh, Water pollution scenario at river uramurukwa flowing through Owerri metropolis, Imo state, Nigeria, Int. J. Environ. Pollut. Res., 6 (2018) 38-49. https://www.eajournals.org/journals/international-journal-of-environment-and-pollution-research-ijepr/
E.N Verla, A.W Verla, C.E Enyoh, Finding a relationship between physicochemical characteristics and ionic composition of River Nworie, Imo State, Nigeria, PeerJ Anal. Chem., 2 (2020) e5. https://doi.org/10.7717/peerj-achem.5
S. Naruka, M.S. Sharma, Water quality assessment of Rajsamand Lake, Rajasthan, India, Int. Res. J. Environ. Sci., 6 (2017) 22-28. https://portal.issn.org/resource/ISSN/2319-1414
C.E. Duru, I.P. Okoro, C.E. Enyoh, Quality assessment of borehole water within Orji mechanic village using pollution and contamination models, Int. J. Chem., Mater. Environ. Res., 4 (2017) 123-130. https://portal.issn.org/resource/ISSN/2410-5945
F.C. Ibe, A.I. Opara, B.O. Ibe, C.E. Amaobi, Application of assessment models for pollution and health risk from effluent discharge into a tropical stream: case study of Inyishi River, Southeastern Nigeria, Environ. Monit. Assess., 19 (2019) 191-753. https://doi.org/10.1007/s10661-019-7936-8
A.A. Bordalo, R. Teixerra, W. J. Wiebe, Water quality index applied to an international shared river basin: the case of Douro River, Environ. Manage., 38 (2006) 910-920. https://doi.org/10.1007/s00267-004-0037-6.
EPA (Environmental Protection Agency), Risk assessment guidance for superfund, vol. 1, human health evaluation manual, part A, Report EPA/540/1-89/002, Washington, DC., 1989. https://www.epa.gov/sites/default/files/2015-09/documents/rags_a.pdf
S.Y. Li, Q.F. Zhang, Spatial characterization of dissolved trace elements and trace metals in the upper Han River (China) using multivariate statistical techniques, J. Hazard. Mater., 176 (2010) 579–588. https://doi.org/10.1016/j.jhazmat.2009.11.069
A.O. Eludoyin, O.T. Oyeku, Heavy metal contamination of groundwater resources in a Nigerian urban settlement, African J. Environ. Sci. Technol., 4 (2010) 201-214. https://doi.org/10.1007/s00128-008-9497-3.
EPA (Environmental Protection Agency), Water monitoring and assessment, Retrieved October 14, 2009. http://water.epa.gov/type/rsl/monitoring/vms510.cfm
B. Wu, D.Y, Zhao, H.Y. Jia, Y. Zhang, X.X. Zhang, S. P. Cheng, Preliminary risk assessment of trace metal pollution in surface water from Yangtze River in Nanjing Section, China, Bull. Environ. Contam. Toxicol., 82 (2009) 405–409. https://doi.org/10.1007/s00128-008-9497-3.
J. Iqbal, M.H. Shah, Health risk assessment of metals in surface water from freshwater source lakes Pakistan, Human Ecolol. Risk Asses. Int. J., 19 (2013) 1530–1543. https://doi.org/10.1080/10807039.2012.716681
S. Giandomenico, N. Cardellicchio, L. Spada, C. Annicchiarico, A. Di Leo, Metals and PCB levels in some edible marine organisms from the Ionian Sea: dietary intake evaluation and risk for consumers, Environ. Sci. Pollut. Res., 23 (2016) 12596–12612. https://doi.org/10.1007/s11356-015-5280-2.
S. Sudsandee, K. Tantrakarnapa, P. Tharnpoophasiam, Y. Limpanont, R. Mingkhwan, S. Worakhunpiset, Evaluating health risks posed by heavy metals to humans consuming blood cockles (Anadara granosa) from the Upper Gulf of Thailand, Environ. Sci. Pollut. Res., 24 (2017) 14605–14615. https://doi.org/10.1007/s11356-017-9014-5
L. Yonglong, S. Song, R. Wang, Impacts of soil and water pollution on food safety and health risks in China, Int. J. Environ., 77 (2015) 5-15. https://doi.org/10.1016/j.envint.2014.12.010.
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