Magnetic solid-phase extraction based on the Carbonized cotton fabric/zeolite imidazolate framework-71/Fe3O4/polythionine followed by atomic absorption spectrometry for cadmium monitoring in water, tomato and cabbage samples

Volume 5, Issue 02, Pages 60-75, Jun 2022 *** Field: Analytical chemistry by nanoadsorbent

  • Yasaman Sanaei Department of Applied Chemistry, Faculty of Science, South Tehran Branch, Islamic Azad University, Tehran, Iran
  • Mohsen Zeeb, Corresponding Author, Department of Applied Chemistry, Faculty of Science, South Tehran Branch, Islamic Azad University, Tehran, Iran
  • Seyed Saied Homami Department of Applied Chemistry, Faculty of Science, South Tehran Branch, Islamic Azad University, Tehran, Iran.
  • Amirhossein Monzavi Department of Polymer and Textile Engineering, South Tehran Branch, Islamic Azad University, Tehran, Iran
  • Zahra Khodadadi Department of Applied Chemistry, Faculty of Science, South Tehran Branch, Islamic Azad University, Tehran, Iran
DOI: https://doi.org/10.24200/amecj.v5.i02.186
Keywords: Magnetic solid-phase extraction, Flame atomic absorption spectrometry, Cadmium, Carbonized cotton fabric, Zeolite imidazolate framework-71/ Fe3O4/ Polythionine

Abstract

Carbonized cotton fabric/zeolite imidazolate framework-71/Fe3O4/polythionine (CCF/ZIF-71/Fe3O4/PTh) was fabricated, characterized, and applied as efficient magnetic sorbent in magnetic solid-phase extraction (MSPE) of cadmium from water and food samples before determination by flame atomic absorption spectrometry (FAAS). This modification of carbonized cotton fabric led to making a great surface area and porosity, increase extraction efficiency, and acceptable selectivity. The characterization of this proposed sorbent was performed by X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), and Fourier transform-infrared (FT-IR) spectroscopy analysis techniques. The impact of several analytical parameters including pH, sorbent dosage, time of extraction, desorption condition, chelating agent concentration, the amount of salt and effect of potentially interfering ions on the selectivity and extraction recoveries of cadmium, were evaluated and optimized. In this proposed methodology, the limit of detection (LOD), the limit of quantification (LOQ), and relative standard deviation (RSD, n = 3) were found to be 0.21 ng mL−1, 0.6 ng mL−1 and lower than 3.0%, respectively. The validation and accuracy of the new advanced procedure were confirmed by applying the proposed procedure for certified reference materials (SRM1570A). Eventually, CCF/ZIF-71/Fe3O4/PTh can be utilized as a selective sorbent, for the rapid, accurate and sensitive determination of Cd (II)  in the samples.

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Published
2022-06-29
How to Cite
Sanaei, Y., Zeeb, M., Homami, S. S., Monzavi, A., & Khodadadi, Z. (2022). Magnetic solid-phase extraction based on the Carbonized cotton fabric/zeolite imidazolate framework-71/Fe3O4/polythionine followed by atomic absorption spectrometry for cadmium monitoring in water, tomato and cabbage samples. Analytical Methods in Environmental Chemistry Journal, 5(02), 60-75. https://doi.org/10.24200/amecj.v5.i02.186
Issue
Vol 5 No 02 (2022): Issue No Two
Section
Original Article

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