A magnetic graphitic carbon nitride as a new adsorbent for simple separation of Ni (II) ion from foodstuff by ultrasound-assisted magnetic dispersive micro solid-phase extraction method

Volume1,Issue01,Pages47-56,Ar-AMC-36 *** Filed: Food Analysis

  • bahareh Fahimirad semnan university
  • Alireza Asghari
Keywords: g-C3N4, Ni (II), vegetables, SPE, SnFe2O4

Abstract

In this research, a magnetic graphitic carbon nitride (g-C3N4-SnFe2O4) was successfully synthesized and utilized as an efficient adsorbent for nickel (Ni2+) separation/extraction from vegetable samples by ultrasound-assisted magnetic dispersive micro solid-phase extraction (UA-M-D-μSPE). After separation and preconcentration step, Ni ions were determined via micro-sampling flame atomic absorption spectrometry (MS-FAAS). A successful synthesis of g-C3N4-SnFe2O4 was investigated by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and vibrating sample magnetometer (VSM). The optimization of adsorption and desorption steps was effectively studied by the on-at-a time method. In addition, under the optimum experimental conditions, the limits of detection (LODs), the linear ranges (LR) and relative standard deviations (RSDs%, for n = 5) were obtained 1.0 μg.L−1, 4.0 ─ 500.0 μg.L−1, and 1.4 respectively.

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Published
2018-12-28
How to Cite
Fahimirad, bahareh, & Asghari, A. (2018). A magnetic graphitic carbon nitride as a new adsorbent for simple separation of Ni (II) ion from foodstuff by ultrasound-assisted magnetic dispersive micro solid-phase extraction method. Analytical Methods in Environmental Chemistry Journal, 1(01), 47-56. https://doi.org/10.24200/amecj.v1.i01.36
Section
Original Article