A new kinetic models analysis for CO adsorption on palladium zeolite nanostructure by roll-coating technique
Volume 3, Issue 02, Pages 92-107, Jun 2020 *** Field: Environmental Analytical Chemistry
Abstract
The aim of this article was the fabrication of Al2O3/Pd(NO3)2/zeolite adsorbent through roll-coating technique for CO gas adsorption. Transmission electron microscopy (TEM), field-emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), and energy-dispersive x-ray spectroscopy (EDX) were performed to investigate the morphological, structural, and elemental properties of Al2O3/Pd(NO3)2/zeolite adsorbent. A continuous gas analyzer KIMO KIGAZ 210 was applied for testing CO gas adsorption on as-present adsorbent in an experimental set-up. The calculated amounts of adsorption capacity at equilibrium time was 111.16 mg g-1 according to the previous published article. The Elovich, Avrami, and Fractional power kinetic models were studied for this adsorbent. The equal value of experimental and theoretical adsorption capacity at equilibrium time as well as the unit value of regression coefficient indicate that Avrami kinetic model was a suitable model to describe Co removal through Al2O3/Pd(NO3)2/zeolite adsorbent.
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