Solid phase microextraction of organochlorine pesticides in water using MWCNTs-doped polypyrrole coated on steel fiber

Volume 3, Issue 04, Pages 40-51, Dec 2020 *** Field: Analytical Environmental Chemistry

  • Hamideh asadollahzadeh, (*Corresponding Author) Department of Chemistry, Kerman Branch, Islamic Azad University
  • Ebrahim Noroozian Department of Chemistry, Shahid Bahonar University of Kerman, P.O. Box 133-76175, Kerman, Iran
DOI: https://doi.org/10.24200/amecj.v3.i04.117
Keywords: Organochlorine pesticides, Multiwalled carbon nanotubes, Polypyrrole composite, Solid phase microextraction, Gas chromatography

Abstract

The analysis of organochlorine pesticides (OCPs) residues has received an increasing attention in the last decades. Solid-phase microextration (SPME) is a convenient and fast analytical method, which has been widely used for the determination of volatile and semivolatile organic compounds in aqueous samples. The multiwalled carbon nanotubes/polypyrrole composite coating was used for the SPME of OCPs in water samples. The effects of various parameters on the efficiency of SPME process such as extraction time, extraction temperature, ionic strength, desorption time, and desorption temperature were studied. Under optimized conditions, the detection limits for the OCPs varied between 0.051 and 0.39 pg mL-1, the inter-day and intra-day relative standard deviations for various OCPs using a single fiber were 6.5-11.5% and 3.6-11.5, respectively. The linear ranges varied between 0.001 and 1 ng mL-1. The method was successfully applied to the analysis of ground water samples with the recoveries from 86 to 110%.

References

R. Jayaraj, P. Megha, P. Sreedev, Review Article. Organochlorine pesticides, their toxic effects on living organisms and their fate in the environment, Interdiscip.Toxicol. 9 (2016) 90-100.

A. Taghani, N. Goudarzi, G. Bagherian, Application of multiwalled carbon nanotubes for the preconcentration and determination of organochlorine pesticides in water samples by gas chromatography with mass spectrometry, J. Sep. Sci. 39 (2016) 4219-4226.

R. Kumar, S. Mukherji, Threat Posed by Persistent Organochlorine Pesticides and their Mobility in the Environment, Curr. Org. Chem. 22 (2017) 954-972.

A. A. Hassan, M. Sajid, H. Al Ghafly, Kh. Alhooshani, Ionic liquid-based membrane-protected micro-solid-phase extraction of organochlorine pesticides in environmental water samples, Microchemical Journal, 158 (2020) 105295.

J.J. Jiménez, J.L. Bernal, M.J. del Nozal, C. Alonso, Liquid-liquid extraction followed by solid phase extraction for the determination of lipophilic pesticides in beeswax by gas chromatography electron capture detection and matrix matched calibration. J. Chromatogr. A, 1048 (2004) 1048, 89-97.

L. Chen, L. Ding, H. Jin, D. Song, H. Zhang, J. Li, K. Zhang, Y. Wang, H. Zhang, The determination of organochlorine pesticides based on dynamic microwave-assisted extraction coupled with on-line solid-phase extraction of high performance liquid chromatography. Anal. Chim. Acta, 589 (2007) 239-246.

X. Zang, G. Zhang, C. Wang, Z. Wang, Recent developments of dispersive liquid liquid

microextraction technique, Chinese J. Chromatogr. (Se Pu) 33 (2015) 103-111

A. Jain, K.K. Verma, Single-drop microextraction, in: Liq. Extr., Elsevier, 2019: pp.

-472.

M. Sajid, Porous membrane protected micro-solid-phase extraction: A review of features, advancements and applications, Anal. Chim. Acta. 965 (2017) 36-53.

M. Ghorbani, M. Aghamohammadhassan, M. Chamsaz, H. Akhlaghi, T. Pedramrad, Dispersive solid phase microextraction, TrAC - Trends Anal. Chem. 118 (2019) 793-809.

N. Ochiai, K. Sasamoto, H. Kanda, S. Nakamura, Fast screening of pesticide multiresidues in aqueous samples by dual stir bar sorptive extraction-thermal desorption-low thermal mass gas chromatography-mass spectrometry, J. Chromatogr. A. 1130 (2006) 83-90.

R.G. Belardi, J. Pawliszyn, Application of chemically modified fused silica fibers in the extraction of organics from water matrix samples and their rapid transfer to capillary columns, Water. Pollut. Res. J. Can. 24 (1989) 179-191.

X. Li, M. Zhong, J. Chen, Electrodeposited polyaniline as a fiber coating for solid-phase microextraction of organochlorine pesticides from water, J. Sep. Sci. 31 (2008) 2839-2845.

A. Mehdinia, F. Bashour, F. Roohi, A. Jabbari, A. Saleh, Preparation and evaluation of

thermally stable nano-structured self-doped polythiophene coating for analysis of phthalate ester trace levels, J. Sep. Sci. 35 (2012) 563-570

K.C.D.P. Roux, E.F. Jasinski, J. Merib, M.L. Sartorelli, E.Carasek, Application of a robust solid-phase microextraction fiber consisting of NiTi wires coated with polypyrrole for the determination of haloanisoles in water and wine, Anal. Methods. 8 (2016) 5503-5510.

A. Mollahosseini, E. Noroozian, Polyphosphate-doped polypyrrole coated on steel fiber for the solid-phase microextraction of organochlorine pesticides in water, Anal. Chim. Acta. 638 (2009) 169-174.

Y. Jia, H. Su, Z. Wang, Y.-L.L.E. Wong, X. Chen, M. Wang, T.-W.W.D. Chan, Metal-Organic 587 Framework@Microporous Organic Network as Adsorbent for Solid-Phase Microextraction, Anal. 588 Chem. 88 (2016) 9364–9367.

A. Gutiérrez-Serpa, P.I. Napolitano-Tabares, V. Pino, F. Jiménez-Moreno, A.I. Jiménez-Abizanda, Silver nanoparticles supported onto a stainless steel wire for direct-immersion solid-phase microextraction of polycyclic aromatic hydrocarbons prior to their determination by GC-FID, Microchim. Acta. 185 (2018) 341.

A. Gutiérrez-Serpa, P. Rocío-Bautista, V. Pino, F. Jiménez-Moreno, A.I. Jiménez-Abizanda, Gold nanoparticles based solid-phase microextraction coatings for determining organochlorine pesticides in aqueous environmental samples, J. Sep. Sci. 40 (2017) 2009–2021.

M. Sajid, C. Basheer, Layered double hydroxides: Emerging sorbent materials for analytical extractions, TrAC, Trends Anal. Chem. 75 (2016) 174-182

B.B. Prasad, A. Srivastava, M.P. Tiwari, Highly sensitive and selective hyphenated technique (molecularly imprinted polymer solid-phase microextraction-molecularly imprinted polymer sensor) for ultra trace analysis of aspartic acid enantiomers, J. Chromatogr. A 1283 (2013) 9-19.

J. Lu, J. Liu, Y. Wei, K. Jiang, S. Fan, J. Liu, G. Jiang, Preparation of single-walled carbon nanotube fiber coating for solid-phase microextraction of organochlorine pesticides in lake water and wastewater, J. Sep. Sci. 30 (2007) 2138-2143.

M.M. Abolghasemi, V. Yousefi, M. Piryaei, Synthesis of carbon nanotube/layered double hydroxide nanocomposite as a novel fiber coating for the headspace solid-phase microextraction of phenols from water samples J. Sep. Sci. 38 (2015) 1344-1350.

H. Asadollahzadeh, E. Noroozian, Sh. Maghsoudi, Solid phase microextraction of phthalate esters from aqueous media by electrochemically deposited carbon nanotube/polypyrrole composite on a stainless steel fiber, Anal. Chim. Acta, 669 (2010) 32-38.

J. Pawliszyn, Solid Phase Microextraction: Theory and Practice, Wiley-VCH, USA, 1997.

J.P. Pérez-Trujillo, S. Frías, M.J. Sáchez, J.E. Conde, M.A. Rodríguez-Delgado, Determination of organochlorine pesticides by gas chromatography with solid-phase microextraction, Chromatographia, 2002, 56, 191-197.

C. Gonçalves, M.F. Alpendurada, Solid phase microextraction gas chromatography-(tandem) mass spectrometry as a tool for pesticide residue analysis in water sample at high sensitivity and selectivity with confirmation capabilities, J. Chromatogr. A, 2004, 1026, 239-250.

Published
2020-12-29
How to Cite
asadollahzadeh, H., & Noroozian, E. (2020). Solid phase microextraction of organochlorine pesticides in water using MWCNTs-doped polypyrrole coated on steel fiber. Analytical Methods in Environmental Chemistry Journal, 3(04), 40-51. https://doi.org/10.24200/amecj.v3.i04.117
Issue
Vol 3 No 04 (2020): Issue No. four
Section
Original Article

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