Analysis of complexation between new bidentate bis-NHC ligand and some metal cations at different temperature

Volume 5, Issue 02, Pages 5-23, Jun 2022 *** Field:Analysis of Environment samples

  • Nur Rahimah Said School of Chemistry and Environment, Faculty of Applied Sciences, Universiti Teknologi MARA (UiTM), Cawangan Negeri Sembilan, Kampus Kuala Pilah, 72000 Kuala Pilah, Negeri Sembilan, Malaysia
  • Majid Rezayi, Corresponding Author, Medical Toxicology Research Center, Mashhad University of Medical Sciences, Mashhad, Iran; Metabolic Syndrome Research Center, Mashhad University of Medical Science, Mashhad, Iran
  • Ninie Suhana Abdul Manan Department of Chemistry, Faculty of Science, University of Malaya Centre for Ionic Liquids, University of Malaya, 50603, Kuala Lumpur, Malaysia Department of Chemistry, Faculty of Science, University of Malaya, Kuala Lumpur 50603, Malaysia
  • Amirhossein Sahebkar Mashhad University of Medical Sciences, Mashhad, Iran
  • Yatimah Alias, Corresponding Author, Department of Chemistry, Faculty of Science, University of Malaya Centre for Ionic Liquids, University of Malaya, 50603, Kuala Lumpur, Malaysia ; Department of Chemistry, Faculty of Science, University of Malaya, Kuala Lumpur 50603, Malaysia
DOI: https://doi.org/10.24200/amecj.v5.i02.169
Keywords: Analysis, Complexation process, Ligand, Conductometric method, Binary mixed solvent, Thermodynamic parameters

Abstract

In this research, the determination and complexation process between 3,3'-(2,2'-(4-methyl-phenylenesulfonamido)bis(ethane-2,1-diyl))bis(1-benzyl-3H-benzo[d]imidazol-1-ium)dibromide with Ni2+, Zn2+, Pd2+, Ag+, and Hg2+ cations in the binary mixture of methanol (MeOH) and water (H2O) at different temperatures (15, 25, 35 and 45ºC) were studied using a conductometric method. The results show that the stoichiometry of the complexes in all binary mixed solvents for Ni2+, Zn2+, and Pd2+ were 1:1 (M:L), while in other cases 1:2 (M:L) and 2:1(M:L). The stability constants (log ) of complex formation have been determined by fitting molar conductivity curves using a computer program (GENPLOT). The obtained data shows that in the pure methanol solvent system, the stability order is Ni2+< Pd2+<Zn2+<Hg2+<Ag+ and the complexation process seems more stable in pure methanol in most cases. The thermodynamic parameters were determined conductometrically. The complexes in all cases were found to be enthalpy destabilized but entropy stabilized. The experimental data was tested by using an artificial neural network (ANN) program and was in good agreement with the estimated data.

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Published
2022-06-28
How to Cite
Said, N. R., Rezayi, M., Abdul Manan, N. S., Sahebkar, A., & Alias, Y. (2022). Analysis of complexation between new bidentate bis-NHC ligand and some metal cations at different temperature. Analytical Methods in Environmental Chemistry Journal, 5(02), 5-23. https://doi.org/10.24200/amecj.v5.i02.169
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Vol 5 No 02 (2022): Issue No Two
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