Fabrication of electrochemical sensor biosystems through hexagonal boron nitride Nanosheets for extraction lead in human serum

Volume 3, Issue 01, Pages 27-40, Mar 2020 *** Field: Nano Chemistry

  • Alisha Saanvi Department of Chemistry, Indian Institute for Advanced Materials
  • Ringo Krishnan Department of Chemistry, Indian Institute for Advanced Materials, India
  • Amoli Hassan Department of Chemistry, Indian Institute for Advanced Materials, India
  • Rmesh K. Gupta*© Corresponding Author: Department of Chemistry, Indian Institute for Advanced Materials, India
DOI: https://doi.org/10.24200/amecj.v3.i01.89
Keywords: Boron nitride nanosheets, Triazine azide, Lead, L-cysteine, Electrochemical Sensor, Solid phase extraction

Abstract

In recent years have seen a surge of increased interest in the exfoliation of boron nitride (h-BN) due to its exciting electrical, thermal, photonics mechanical properties and sensing. Several approach to have emerged describing the exfoliation, functionalized and solubilization of h-BN. In this study, we report on a straightforward approach to modify the surface and its application as a new type of biomedical applications. The prepared product is structurally characterized by FTIR spectroscopy, field emission (FESEM), TGA technique, XPS spectrum, and BET surface area measurements. Nano- composites were immobilized on electrodes to detect the glucose, L-cysteine in buffer medium by cyclic voltammetry (CV), square wave voltammetry (SWV), and impedance spectroscopic (EIS). potential application of the covalent functionalization, cheap precursors, biodegradability and multifunctionality of high-performance composites boron nitride, they could be used for a wide range of the future biomedical applications.

References

P. Moon, M. Koshino, Electronic properties of graphene/hexagonal-boron-nitride moiré superlattice, Phys. Rev., 90 (2014) 155406.

M. Onodera, K. Watanabe, M. Isayama, M. Arai, S. Masubuchi, R. Moriya, T. Taniguchi, T. Machida, Carbon-rich domain in hexagonal boron nitride: carrier mobility degradation and anomalous bending of the landau fan diagram in adjacent grapheme, Nano Lett. (2019) 7282–7286.

S. M. Mostafavi A. Rouhollahi, M. Adibi, F. Pashaee, M. Piryaei, Electrochemical investigation of thiophene on glassy carbon electrode and quantitative determination of it in simulated oil solution by differential pulse voltammetry and amperometry techniques, Asian J. Chem. 23 (2011) 5356-60.

O. Zabihi, A. Khodabandeh, S. M. Mostafavi, Preparation, optimization and thermal characterization of a novel conductive thermoset nanocomposite containing polythiophene nanoparticles using dynamic thermal analysis, Polymer degra. stability, 97(2012) 3-13.

Y. Kubota, K. Watanabe, O. Tsuda, T. Taniguchi, Deep ultraviolet light-Emitting hexagonal boron nitride synthesized at atmospheric pressure, Sci. 317 (2007) 932–934.

M. Yankowitz, J. Xue, D. Cormode, J. D. Sanchez-Yamagishi, K. Watanabe, T. Taniguchi, P. Jarillo-Herrero, P. Jacquod, B.J. LeRoy, Emergence of superlattice dirac points in graphene on hexagonal boron nitride, Nat. Phys., 8 (2012) 382–386.

T.B. Hoffman, B. Clubine, Y. Zhang, K. Snow, J.H. Edgar, JOptimization of Ni–Cr flux growth for hexagonal boron nitride single crystals, J. Cryst. Growth, 393(2014) 114–118.

S. Liu, R. He, Z. Ye, X. Du, J. Lin, H. Jiang, B. Liu, J.H. Edgar, Large-scale growth of high-quality hexagonal boron nitride crystals at atmospheric pressure from an Fe– Cr flux, Cryst. Growth Des., 17 (2017) 4932–4935.

S. M. Mostafavi, 3D graphene biocatalysts for development of enzymatic biofuel cells: a short review, J. Nanoanal.,. 2 (2015) 57-62.

S. Liu, R. He, L. Xue, J. Li, B. Liu, J.H. Edgar, Single crystal growth of millimeterSized monoisotopic hexagonal boron nitride, Chem. Mater., 30 (2018) 6222–6225.

A.M. Al'Abri, S. Mohamad,S.N. Abdul Halim, N.K. Abu Bakar, Development of magnetic porous coordination polymer adsorbent for the removal and preconcentration of Pb(II) from environmental water samples, Environ. Sci. Pollut. Res. Int., 26 (2019) 11410-11426.

A. Davoudiroknabadi, S. S. Sajadikhah, An introduction to nanotechnology, Mikima Book, 2016. ISBN 978-0994498014

A. Davodiroknabadi, A. A. Pasban, Fundamentals of nanostructure and nanomaterial. Mikima Book, 2016. ISBN 978-0994498223

Y.P. Wang, Y. Sun, B. Xu, X.P. Li, X.H. Wang, H.Q. Zhang, D.Q. Song, Matrix solidphase

dispersion coupled with magnetic ionic liquid dispersive liquid–liquid microextraction for the determination of triazine herbicides in oilseeds, Anal. Chim. Acta 888 (2015) 67–74.

M.G. Silly, P. Jaffrennou, J. Barjon, J.S. Lauret, F. Ducastelle, A. Loiseau, E. Obraztsova, B. Attal-Tretout, E. Rosencher, Luminescence properties of hexagonal boron nitride: cathodoluminescence and photoluminescence spectroscopy measurements, Phys. Rev., 75 (2007) 085205.

T.Y. Zhou, J. Ding, L. Ni, J. Yu, H.Y. Li, H. Ding, Y.H. Chen, L. Ding, Preparation of magnetic superhydrophilic molecularly imprinted resins for detection of triazines in aqueous samples, J. Chromatogr. A 1497 (2017) 38–46.

L. Museur, D. Anglos, J.P. Petitet, J.P. Michel, A.V. Kanaev, Photoluminescence of hexagonal boron nitride: effect of surface oxidation under UV-laser irradiation, J. Lumin., 127 (2007), 595–600.

M. Yankowitz, J. Xue, D. Cormode, J.D. Sanchez-Yamagishi, K. Watanabe, T. Taniguchi, P. Jarillo-Herrero, P. Jacquod, B.J. LeRoy, Emergence of superlattice dirac points in graphene on hexagonal boron nitride, Nat. Phys., 8 (2012) 382–386.

M. Roldán-Pijuán, R. Lucena, M.C. Alcudia-León, S. Cárdenas, M. Valcárcel, Stir octadecyl-modified borosilicate disk for the liquid phase microextraction of triazine herbicides from environmental waters, J. Chromatogr. A 1307 (2013) 58–65.

Y.P. Wang, Y. Sun, B. Xu, X.P. Li, R. Jin, H.Q. Zhang, D.Q. Song, Magnetic ionic liquid-based dispersive liquid–liquid microextraction for the determination of triazine herbicides in vegetable oils by liquid chromatography, J. Chromatogr. A 1373 (2014) 9–16.

X. Yang, R. Yu, S.H. Zhang, B.C. Cao, Z.L. Liu, L. Lei, N. Li, Z.B. Wang, L.Y. Zhang, H.Q. Zhang, Aqueous two-phase extraction for determination of triazine herbicides in milk by high-performance liquid chromatography, J. Chromatogr. B 972 (2014) 111–116.

G. Cassabois, P. Valvin, B. Gil, Hexagonal boron nitride is an indirect bandgap semiconductor, Nat. Photonics , 10 (2016) 262–266.

D. Rhodes, S.H. Chae, R. Ribeiro-Palau, J. Hone, Disorder in van der waals heterostructures of 2D materials, Nat. Mater., 18 (2019) 541–549.

K. Watanabe, T. Taniguchi, H. Kanda, Direct-bandgap properties and evidence for ultraviolet lasing of hexagonal boron nitride single crystal. Nat. Mater., 3 (2004) 404–409.

T. Yamaguchi, Y. Inoue, S. Masubuchi, S. Morikawa, M. Onuki, K. Watanabe, T. Taniguchi, R. Moriya, T. Machida, Electrical spin injection into graphene through monolayer hexagonal boron nitride, Appl. Phys. Express , 6 (2013) 073001.

L. Britnell, R.V. Gorbachev, R. Jalil, B.D. Belle, F. Schedin, M.I. Katsnelson, L. Eaves, S.V. Morozov, A.S. Mayorov, N.M.R Peres, A.H. Castro Neto, J. Leist, A.K. Geim, L.A. Ponomarenko, K.S. Novoselov, Electron tunneling through ultrathin, boron nitride crystalline barriers, Nano Lett., 12 (2012) 1707–1710.

S. Jafari, S. A. Mostafavi, Investigation of nitrogen contamination of important subterranean water in the plain, Med. Biotech., J. 3 (2019) 10-12.

S.J. Grenadier, A. Maity, J. Li, J.Y. Lin, H.X. Jiang, Origin and roles of oxygen impurities in hexagonal boron nitride epilayers, Appl. Phys. Lett., 112 (2018) 162103.

S. M. Mostafavi, H. Malekzadeh, M. S. Taskhiri, In silico prediction of gas chromatographic retention time of some organic compounds on the modified carbon nanotube capillary column, J. Com. Theor. Nanosci. 16 (2019) 151-156.

S. Nekouei, F. Nekouei, I. Tyagi, S. Agarwal, V. K. Gupta, Mixed cloud point/solid phase extraction of lead(II) andcadmium(II) in water samples using modified-ZnO nano-powders, Process Saf. Environ. Protection, 99 (2016)175–185 .

Published
2020-03-29
How to Cite
Saanvi, A., Krishnan, R., Hassan, A., & K. Gupta*©R. (2020). Fabrication of electrochemical sensor biosystems through hexagonal boron nitride Nanosheets for extraction lead in human serum. Analytical Methods in Environmental Chemistry Journal, 3(01), 49-54. https://doi.org/10.24200/amecj.v3.i01.89
Issue
Vol 3 No 01 (2020): Issue No. One
Section
Original Article

Copyright (c) 2020 Analytical Methods in Environmental Chemistry Journal

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